advanced materials for electrodes and electrolyte in rechargeable lithium batteries
共233页。
CHAPTER 1 INTRODUCTION
1.1 Motivation
1.2 Importance of Study
1.3 Goals of the work
CHAPTER 2 LITERATURE REVIEW
2.1 Rechargeable Lithium Batteries
2.1.1 History of the batteries
2.1.2 Primary Lithium Batteries
2.1.3 Secondary Lithium Batteries
2.1.4 Principles of Operation
2.1.5 Advantages and Commercial Applications
2.1.6 The Challenges
2.1.6.1 Materials and Cost
2.1.6.2 Safety
2.1.6.3 Aging
2.2 Negative Electrode Materials
2.2.1 Carbonaceous Materials
2.2.2 Lithium-Metal Alloys
2.2.3 Titanium Compounds
2.3 Positive Electrode Materials
2.3.1 Layered Transition Metal Oxides
2.3.2 Spinel Oxide
2.3.3 Olivine
2.3.4 Vanadates
2.4 Electrolytes
2.4.1 Polymer Electrolytes
2.4.2 Ionic Liquids
2.5 Current Manufacturing Technology and Future
Prospects
CHAPTER 3 EXPERIMENTAL DETAILS
3.1 Overview
3.2 List of Materials
3.3 Method of Synthesis
3.3.1 Vacuum Filtration Technique
3.3.2 Flame Spray Deposition
3.3.3 Polyol-Mediated Synthetic Method
3.3.4 Sol-Gel method
3.3.5 In Situ Oxidative Chemical Polymerization
3.3.5.1 Preparation of Si-PPy
3.3.5.2 Preparation of LiV3O8-PPy
3.3.6 Preparation of IL-PE Composite Membrane
3.3.6.1 Synthesis of Room Temperature
Ionic Liquid(RTIL),N-methyl-N-
propyl pyrrolidinium
bis(trifluoromethanesulfonyl)amide
[P13TFSA]
3.3.6.2 Synthesis of Zwitterionic
Compound(ZW),1-
butylimidazolium-3-(n-
butanesulfonate)
3.4 Physical and Structural Characterization
3.4.1 X-Ray Diffraction(XRD)
3.4.2 Raman Spectroscopy
3.4.3 Fourier Transform Infrared(FT-IR)
Spectroscopy
3.4.4 Thermogravimetric Analysis(TGA)
3.4.5 Scanning Electron Microscopy(SEM)
3.4.6 Transmission Electron Microscopy(TEM)
3.4.7 Brunauer Emmett Teller(BET)
Adsorption/Desorption Measurement
3.4.8 Ionic Conductivity Measurement
3.4.9 Tensile Strength Measurement
3.5 Electrode Preparation and Test Cell Assembly
3.5.1 Electrode Preparation
3.5.2 Test Cell Assembly
3.6 Electrochemical Characterization
3.6.1 Cyclic Voltammetry(CV)
3.6.2 Galvanostatic Cycling Measurements
3.6.3 Electrochemical Impedance Spectroscopy
(EIS)
CHAPTER 4 FREE-STANDING CARBON NANOTUBE FILMS AS ANODES
FOR LI-ION BATTERIES
4.1 Introduction
4.2 Preparation of CNT Films
4.3 Electrochemical Measurements
4.4 Physical and Structural Characterizations
4.5 Electrochemical Performance
4.6 Conclusions
CHAPTER 5 NANOSTRUCTURED LIMN2O4 THIN FILM CATHODE BY
THE FLAME SPRAY DEPOSITION METHOD
5.1 Introduction
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