摘要翻译:
综述了计算单组分和多组分硬球流体结构和热力学性质的一些分析方法。对于结构性质,它们得到了热力学一致的公式,从而改进和推广了Percus-Yevick理论的已知分析结果。文中还讨论了径向分布函数接触值的近似表达式和相应的解析状态方程。本文简要介绍了该方法在相关系统中的推广,如粘硬球和方井流体,以及它在流体微扰理论中的应用。
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英文标题:
《Alternative Approaches to the Equilibrium Properties of Hard-Sphere
Liquids》
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作者:
M. Lopez de Haro, S. B. Yuste, and A. Santos
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最新提交年份:
2007
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分类信息:
一级分类:Physics 物理学
二级分类:Statistical Mechanics 统计力学
分类描述:Phase transitions, thermodynamics, field theory, non-equilibrium phenomena, renormalization group and scaling, integrable models, turbulence
相变,热力学,场论,非平衡现象,重整化群和标度,可积模型,湍流
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一级分类:Physics 物理学
二级分类:Soft Condensed Matter 软凝聚态物质
分类描述:Membranes, polymers, liquid crystals, glasses, colloids, granular matter
膜,聚合物,液晶,玻璃,胶体,颗粒物质
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一级分类:Physics 物理学
二级分类:Chemical Physics 化学物理学
分类描述:Experimental, computational, and theoretical physics of atoms, molecules, and clusters - Classical and quantum description of states, processes, and dynamics; spectroscopy, electronic structure, conformations, reactions, interactions, and phases. Chemical thermodynamics. Disperse systems. High pressure chemistry. Solid state chemistry. Surface and interface chemistry.
原子、分子和团簇的实验、计算和理论物理-状态、过程和动力学的经典和量子描述;光谱学,电子结构,构象,反应,相互作用和相。化学热力学。分散系统。高压化学。固态化学。表面和界面化学。
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英文摘要:
An overview of some analytical approaches to the computation of the structural and thermodynamic properties of single component and multicomponent hard-sphere fluids is provided. For the structural properties, they yield a thermodynamically consistent formulation, thus improving and extending the known analytical results of the Percus-Yevick theory. Approximate expressions for the contact values of the radial distribution functions and the corresponding analytical equations of state are also discussed. Extensions of this methodology to related systems, such as sticky hard spheres and square-well fluids, as well as its use in connection with the perturbation theory of fluids are briefly addressed.
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PDF链接:
https://arxiv.org/pdf/704.0157