摘要翻译:
在单晶硅膜中,氦和氩气体通过直径为12纳米、长度为200微米的平行线性通道的实验研究表明,在Kn范围内,氦和氩气体在10^2~10^7范围内存在Knudsen扩散型输运。在40~300K范围内,对He和D_He/D_Ar~sqrt(M_Ar/M_He)的比值,证实了经典标度法对扩散物种的温度和质量对迁移扩散系数D_He~sqrt(T)的预测。与理想管状通道中的Knudsen扩散相比,通道偏离圆柱形的程度可以用透射电子显微镜分辨到亚纳米尺度,定量地解释了扩散率降低的原因。用Beskok和Karniadakis的统一流动模型描述了在Kn范围内10个数量级以上的膜渗透实验,包括过渡流区。
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英文标题:
《Knudsen Diffusion in Silicon Nanochannels》
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作者:
Simon Gruener and Patrick Huber
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最新提交年份:
2008
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分类信息:
一级分类:Physics 物理学
二级分类:Fluid Dynamics 流体动力学
分类描述:Turbulence, instabilities, incompressible/compressible flows, reacting flows. Aero/hydrodynamics, fluid-structure interactions, acoustics. Biological fluid dynamics, micro/nanofluidics, interfacial phenomena. Complex fluids, suspensions and granular flows, porous media flows. Geophysical flows, thermoconvective and stratified flows. Mathematical and computational methods for fluid dynamics, fluid flow models, experimental techniques.
湍流,不稳定性,不可压缩/可压缩流,反应流。气动/流体力学,流体-结构相互作用,声学。生物流体力学,微/纳米流体力学,界面现象。复杂流体,悬浮液和颗粒流,多孔介质流。地球物理流,热对流和层流。流体动力学的数学和计算方法,流体流动模型,实验技术。
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一级分类:Physics 物理学
二级分类:Materials Science 材料科学
分类描述:Techniques, synthesis, characterization, structure. Structural phase transitions, mechanical properties, phonons. Defects, adsorbates, interfaces
技术,合成,表征,结构。结构相变,力学性质,声子。缺陷,吸附质,界面
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一级分类:Physics 物理学
二级分类:Statistical Mechanics 统计力学
分类描述:Phase transitions, thermodynamics, field theory, non-equilibrium phenomena, renormalization group and scaling, integrable models, turbulence
相变,热力学,场论,非平衡现象,重整化群和标度,可积模型,湍流
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一级分类:Physics 物理学
二级分类:Exactly Solvable and Integrable Systems 精确可解可积系统
分类描述:Exactly solvable systems, integrable PDEs, integrable ODEs, Painleve analysis, integrable discrete maps, solvable lattice models, integrable quantum systems
精确可解系统,可积偏微分方程,可积偏微分方程,Painleve分析,可积离散映射,可解格模型,可积量子系统
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一级分类:Physics 物理学
二级分类:Chemical Physics 化学物理学
分类描述:Experimental, computational, and theoretical physics of atoms, molecules, and clusters - Classical and quantum description of states, processes, and dynamics; spectroscopy, electronic structure, conformations, reactions, interactions, and phases. Chemical thermodynamics. Disperse systems. High pressure chemistry. Solid state chemistry. Surface and interface chemistry.
原子、分子和团簇的实验、计算和理论物理-状态、过程和动力学的经典和量子描述;光谱学,电子结构,构象,反应,相互作用和相。化学热力学。分散系统。高压化学。固态化学。表面和界面化学。
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英文摘要:
Measurements on helium and argon gas flow through an array of parallel, linear channels of 12 nm diameter and 200 micrometer length in a single crystalline silicon membrane reveal a Knudsen diffusion type transport from 10^2 to 10^7 in Knudsen number Kn. The classic scaling prediction for the transport diffusion coefficient on temperature and mass of diffusing species,D_He ~ sqrt(T), is confirmed over a T range from 40 K to 300 K for He and for the ratio of D_He/D_Ar ~ sqrt(m_Ar/m_He). Deviations of the channels from a cylindrical form, resolved with transmission electron microscopy down to subnanometer scales, quantitatively account for a reduced diffusivity as compared to Knudsen diffusion in ideal tubular channels. The membrane permeation experiments are described over 10 orders of magnitude in Kn, encompassing the transition flow regime, by the unified flow model of Beskok and Karniadakis.
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PDF链接:
https://arxiv.org/pdf/802.1852