摘要翻译:
我们对方阱势的气液临界点进行了模拟研究,当阱宽δ小于0.005倍粒子直径σ时。对于较小的delta,临界点b2*c处的约化第二维里系数与delta成线性关系。由于临界温度T_c与B_2*c之间的高度非线性变换,如果通过常数B_2*c假设来估计T_c,所观察到的弱线性依赖不足以产生任何显著的可观测效应。这解释了先前观察到的相应国家法律的有效性。临界密度rho_c以两键合粒子间的立方平均距离(1+0.5δ)/σ为单位测量时也是常数。用精确的函数形式描述delta->0依赖关系的可能性提供了粘着硬球AHS模型临界参数的改进的累计估计。
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英文标题:
《The vanishing limit of the square-well fluid: the adhesive hard sphere
model as a reference system》
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作者:
J. Largo, M.A. Miller, F. Sciortino
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最新提交年份:
2007
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分类信息:
一级分类:Physics 物理学
二级分类:Soft Condensed Matter 软凝聚态物质
分类描述:Membranes, polymers, liquid crystals, glasses, colloids, granular matter
膜,聚合物,液晶,玻璃,胶体,颗粒物质
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一级分类:Physics 物理学
二级分类:Statistical Mechanics 统计力学
分类描述:Phase transitions, thermodynamics, field theory, non-equilibrium phenomena, renormalization group and scaling, integrable models, turbulence
相变,热力学,场论,非平衡现象,重整化群和标度,可积模型,湍流
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英文摘要:
We report a simulation study of the gas-liquid critical point for the square-well potential, for values of well width delta as small as 0.005 times the particle diameter sigma. For small delta, the reduced second virial coefficient at the critical point B_2*c is found to depend linearly on delta. The observed weak linear dependence is not sufficient to produce any significant observable effect if the critical temperature T_c is estimated via a constant B_2*c assumption, due to the highly non linear transformation between B_2*c and T_c. This explains the previously observed validity of the law of corresponding states. The critical density rho_c is also found to be constant when measured in units of the cubed average distance between two bonded particles (1+0.5 delta)/sigma. The possibility of describing the delta -> 0 dependence with precise functional forms provides improved acccurate estimates of the critical parameters of the adhesive hard-sphere AHS model.
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PDF链接:
https://arxiv.org/pdf/712.2934